Stoichiometry


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                                                                        Name _______

CHAPTER 9 – STOICHIOMETERY


STOICHIOMETERY- The study of the amount of a substances consumed and produced in chemical reactions.

The science of reactions is basically like cooking. You must mix the right proportion of each ingredient (reactant) to obtain the best results (products).

The “recipe” for a chemical reaction is the balanced equation.

For Example:      2 H2  +  O2    2H2O
                       
                        This can be read as 2 hydrogen molecules mix with one oxygen molecule
                         to produce 2 water molecules.
                                                 or
                         2 moles of  H2 mix with 1 mole of O2 to make 2 moles of H2O

Example:
                         ___KClO3    ____KCl  +  ____O2

mole ratio step

____moles of KClO3 yields  ____ moles of KCl and ____ moles of O2.

You will use these coefficients (mole ratios) to determine how much you will need to mix together or how much you can produce.

Example of Mole/Mole problems:
1)      How many moles of O2 will 9.5 moles of KClO3 produce?

To solve this problem, we will use the T-bar and add a mole ratio step.  The mole ratio allows you to convert from one substance to another. They are the whole number coefficients that you use to balance the equations.

given                       mole ratio
      9.5 moles KClO3    3 moles of O2____ =  14.25 moles O2
                                     2 moles of KClO3

Try these two on your own:

1)      If you want to produce 15.0 moles of O2, how many moles of KClO3 should you start with?



2).   If 18.2 moles of O2 are produced, how many moles of KCl are produced with it?


The real key to stoichiometry is to obtain numbers we can use in the lab. So, instead of moles, we will want our answers in grams. This requires a conversion from moles to grams using the gfm. ( remember: 1 mole = gfm (gram formula mass )

There are four basic stoichiometry  reactions. Let’s name them and write the formulas:

1)      mole to mole



2)      mole to mass



3)      mass to moles



      4)  mass to mass



Now that we have to four basic types of stoichiometery formulas, lets practice.


CaC2  +  2 H2O    C2H2  +  Ca(OH)2

Moles-mass problems:

1)      How many grams of water are required to produce 1.55 moles of C2H2?



2)      How many grams of C2H2 are produced when 5.0 moles of CaC2 reacts completely?


Mass-moles  problems:

1)      How many moles of water are needed to react with 20.5 g of CaC2?

    

2)      How many moles of Ca(OH)2 are produced with 29.0 g of C2H2?



3)      How many moles of CaC2 will produce 15.0 g of Ca(OH)2?      





The final step in stoichiometry is to start with grams and to end with grams. This way you know what you are going to produce in lab, or how much of each reactant you need to mix.



4        Na  +  O2    2 Na2O

1). How many grams  of O2 are required to react completely with 14.6 g of Na to form Na2O?


2).  How many grams of Na2O are produced when 20.0 g Na reacts completely?


3).  How many grams of Na are needed to produce 200.0 g of Na2O?  



Mole – mole conversions

____CaC2  +    ____ H2O      ____C2H2  +  ____ Ca(OH)2

1)      How many moles of water are needed to react with 2.5 moles of CaC2?



2)      How many moles of C2H2 are produced when 9.5 moles of CaC2 are mixed with excess water?
___________________________________________________________________________

____Na  +  ____ O2     ____Na2O

3)      How many moles of Na are needed to produce 0.25 moles of Na2O?



4)      How many moles of O2 will react with 9.4 moles of Na to produce Na2O?



5)      Calculate the number of moles of Na2O that will be produced when 5.0 moles of Na completely react with oxygen gas?




___C2H6  +  ____O2      ____ CO2  +  ____H2O

6)      How many moles of carbon dioxide are produced when 5.8 moles of C2H6 react completely with oxygen?




7)      How many moles of O2 are needed to react completely with 18.0 moles of CO2?




8)      How many moles of C2H6 are needed to produce 14.0 moles CO2?




9)      If 9.8 moles of CO2 are produced, how many moles of water are also produced?





Gram-mole,   Mole –gram conversions

____C2H6  +  ____O2      ____CO2  +  ____H2O

1)      How many grams of CO2 are produced when you use 8.0 moles of C2H6?




2)      If 8.0 moles of CO2 are produced in this reaction, how many grams of O2 have been used?




3)      45.0 grams of C2H6 will react with oxygen to produce ______ moles of water?




____Cu  +  ____AgNO3      ____Cu(NO3)2  +  ____Ag

4)      How many moles of AgNO3 are needed to react with 170.0 g of Cu?



5)      In a reaction, 8.5 moles Ag are produced. How many grams of Cu were used up in the reaction?


_________________________________________________________________________________

____NH3  +  ____NO    ____N2  +  ____H2O

6)      If 4.5 moles of water are produced, how many grams of NH3 must you start with?



7)      How many moles of NO are needed to react with 48.0 g NH3?



8)      If 9.8 g of N2 are produced, how many moles of water are also produced?



9)  How many moles are NH3 will produce 15.0 g of N2?



Gram-Gram conversions

___Li3N  +  ____H2O    ____NH3  +  ____LiOH

1)      What mass of water is needed to react with 98.7 g of lithium nitride?



2)      How many grams of ammonia will be formed if 36.0  g Li3N reacts completely with water?




____SiO2  +  ____C      ____SiC   +  ____CO

3)      How many grams of SiO2 are needed to react with 45.0 g of C?




4)      If 19.0 of C are used, how many grams of SiC can be produced?





____NH4NO3    ____N2    +  _____O2  +  ____H2O
           
5)      How many grams of water are produced when 45.6 g of ammonium nitrate decomposes?




6)      If 15.5 grams of O2 are formed, how many grams of NH4NO3 must have decomposed?





     7)   If 87.5 g of N2 are produced, how many grams of water are also produced?